2-(4-Bromo­phen­yl)-2-oxoethyl 4-chloro­benzoate

نویسندگان

  • Hoong-Kun Fun
  • Chin Sing Yeap
  • B. Garudachari
  • Arun M. Isloor
  • M. N. Satyanarayan
چکیده

The asymmetric unit of the title compound, C(15)H(10)BrClO(3), consists of three crystallographically independent mol-ecules. The dihedral angles between the benzene rings in the three mol-ecules are 68.8 (2), 0.7 (3) and 66.1 (2)°. In the crystal, the three independent mol-ecules are inter-connected by C-H⋯O hydrogen bonds, leading to isolated trimers.

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منابع مشابه

2-(4-Bromo­phen­yl)-2-oxoethyl 2-meth­oxy­benzoate

In the title mol-ecule, C(16)H(13)BrO(4), the dihedral angle between the benzene rings is 85.92 (10)°. In the crystal, mol-ecules are linked into chains along [100] via weak inter-molecular C-H⋯O hydrogen bonds.

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In the title compound, C(15)H(11)BrO(4), the dihedral angle between the aromatic rings is 66.77 (8)°. In the crystal, O-H⋯O, C-H⋯Br and C-H⋯O hydrogen bonds link the mol-ecules, forming layers lying parallel to (101). The crystal packing is further consolidated by C-H⋯π inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.5476 (7) Å].

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2-(4-Bromo­phen­yl)-2-oxoethyl 4-meth­oxy­benzoate

In the title compound, C(16)H(13)BrO(4), the benzene rings are almost perpendicular to each other, making a dihedral angle of 84.07 (8)°. In the crystal, the mol-ecules are linked into chains along the a axis via inter-molecular C-H⋯O hydrogen bonds. A C-H⋯π inter-action is also observed.

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2-(4-Bromo­phen­yl)-2-oxoethyl 4-methyl­benzoate

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2-(4-Bromo­phen­yl)-2-oxoethyl 2-methyl­benzoate

In the title compound, C(16)H(13)BrO(3), the dihedral angle formed between the bromo- and methyl-substituted benzene rings is 66.66 (8)°. In the crystal, mol-ecules are linked by inter-molecular C-H⋯O hydrogen bonds, forming a two-dimensional network parallel to the ac plane. The crystal packing is further consolidated by C-H⋯π inter-actions.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011